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Geochronology Advances in geochronological science
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Discussion papers
https://doi.org/10.5194/gchron-2019-4
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/gchron-2019-4
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.

Submitted as: research article 05 Jun 2019

Submitted as: research article | 05 Jun 2019

Review status
This discussion paper is a preprint. A revision of the manuscript is under review for the journal Geochronology (GChron).

Stepwise chemical abrasion ID-TIMS-TEA of microfractured Hadean zircon

C. Brenhin Keller1, Patrick Boehnke2, Blair Schoene3, and T. Mark Harrison4 C. Brenhin Keller et al.
  • 1Department of Earth Sciences, Dartmouth College, Hanover, NH 03755
  • 2Eta Vision, Chicago, IL 60611
  • 3Department of Geosciences, Guyot Hall, Princeton University, Princeton, NJ 08544
  • 4Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, CA 90095

Abstract. The Hadean Jack Hills zircons represent the oldest known terrestrial material, providing a unique and truly direct record of Hadean Earth history. This zircon population has been extensively studied via high spatial resolution, high throughput in situ isotopic and elemental analysis techniques such as secondary ionization mass spectrometry (SIMS), but not by comparatively destructive, high-temporal-precision (< 0.05 % two-sigma) thermal ionization mass spectrometry (TIMS). In order to better understand the lead loss and alteration history of terrestrial Hadean zircons, we conduct stepwise chemical abrasion isotope dilution thermal ionization mass spectrometry with trace element analysis (CA-ID-TIMS-TEA) on manually microfractured Hadean Jack Hills zircon fragments previously dated by SIMS. We conducted three successive HF leaching steps on each individual zircon fragment, followed by column chromatography to isolate U-Pb and trace element fractions. Following isotopic and elemental analysis, the result is an independent age and trace element composition for each leachate of each zircon fragment. We observe ~ 50 Myr of age heterogeneity in concordant residues from a single zircon grain, along with a protracted history of post-Hadean Pb-loss with at least two modes circa ~ 0 and 2–4 Ga. Meanwhile, step-wise leachate trace element chemistry reveals enrichments of light rare earth elements, uranium, thorium, and radiogenic lead in early leached domains relative to the zircon residue. In addition to confirming the efficacy of the LREE-I alteration index and providing new insight into the mechanism of chemical abrasion, the interpretation and reconciliation of these results suggests that Pb-loss is largely driven by low-temperature aqueous recrystallization, and that regional thermal events may act to halt – not initiate – Pb-loss from metamict domains in the Hadean Jack Hills zircons.

C. Brenhin Keller et al.
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Stepwise chemical abrasion ID-TIMS-TEA of microfractured Hadean zircon C. Brenhin Keller, P. Boehnke, B. Schoene, and T. Mark Harrison https://doi.org/10.17605/OSF.IO/AVDQH

C. Brenhin Keller et al.
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Latest update: 20 Oct 2019
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Short summary
The oldest known minerals on Earth are Hadean (> 4.0 Ga) zircons from the Jack Hills, Australia. We present the first application to such Hadean zircons of stepwise chemical abrasion isotope dilution thermal ionization mass spectrometry with trace element analysis (stepwise CA-ID-TIMS-TEA). We examine the evolution in U-Pb age and trace element chemistry of zircon domains accessed by successive chemical abrasion steps in the context of the geologic history of the Jack Hills zircons.
The oldest known minerals on Earth are Hadean ( 4.0 Ga) zircons from the Jack Hills, Australia....
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